2-Methoxyimino-2-{2-[(2-methylphenoxy)methyl]phenyl}ethanol
نویسندگان
چکیده
In the title compound, C(17)H(19)NO(3), the dihedral angle between the benzene rings is 68.0 (1)°. The C-O-C-C torsion angle of the atoms joining these rings is 179.7 (2)°. The atoms of the methanol group were refined as disordered over two sets of sites with fixed occupancies of 0.86 and 0.14. The H atoms of the hy-droxy group in the major component are disordered over a further two sets of sites with equal occupancies. This is a necessary arrangement to allow for hydrogen bonding without unrealistic H⋯H contacts. In the crystal, O-H⋯N and O-H⋯O hydrogen bonds connect mol-ecules into chains along [001].
منابع مشابه
5-((Methoxyimino){2-[(2-methylphenoxy)methyl]phenyl}methyl)-N-phenyl-1,3,4-oxadiazol-2-amine
In the title mol-ecule, C24H22N4O3, the plane of the oxa-diazole ring forms a dihedral angle of 32.41 (12)° with that of the phenyl ring and dihedral angles of 74.51 (10) and 56.38 (10)° with the planes of the benzene rings. In the crystal, pairs of N-H⋯N hydrogen bonds link molecules into inversion dimers featuring R 2 (2)(8) graph-set motifs.
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In the title compound, C(17)H(17)NO(4), the dihedral angle between the two aromatic rings is 59.64 (5)°. The (meth-oxy-imino)-ethanoic acid fragment is nearly perpendicular to the attached benzene ring [dihedral angle = 81.07 (4)°]. In the crystal, pairs of O-H⋯O hydrogen bonds between carb-oxy groups link mol-ecules into inversion dimers. In addition, π-π stacking inter-actions between inversi...
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In the title compound, C17H16O4, the dihedral angle between the benzene rings is 4.4 (2)°. In the crystal, weak C-H⋯O hydrogen bonds connect mol-ecules along [001].
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